Main content pitfalls and pratfalls of sampling via summa canister by. Summa canisters are completely evacuated to negative pressure 30hg before use. Parallel sampling of whole air canister samplers and cartridges at field sites. Fittings typically connect the tubing between the subslab probe and the collection container usually a summa canister.
Method sampling guide samples for analysis by method to3 can be gathered as grab samples, or as time composites of 124 hours utilizing a canister and pneumatic flow controller. Additionally, nondisposable fittings may be used for assembly of sample train, shut in testing, or sampling. Initiate the sampling event by turning valve on canister counter clockwise until valve. Photograph the canister and the area surrounding the canister. After cleaning and certification, the summa canisters will be shipped to the field with a vacuum of summa canister samples, collocated sarnples and trip blanks will be included at the rate specified in table 2, footnotes 17, respectively. Compendium of methods for the determination of toxic.
Electropolished stainless steel canisters or silcosteel canisters using. Attach the analog gauge on a swagelok tee to the valve on the. Standard operating procedure for the collection of vocs in ambient air using summa canisters and xontech sampler procedure no. Usa home product directory analyticalchromatography analytical standards additional standards method and regulation specific epa epa to methods to14 summa canister sampling. Canisters and cartridges were deployed sidebyside at each of the sampling sites as shown in figure 3. Evaluation of charcoal tube and summa canister recovery. The summa canister was sent to the field where the investigator. Active sampling requires the use of a pumping device whereas passive sampling does not. Summa canisters summa canisters are the triedandtrue workhorses of vapor intrusion sampling. Compendium of methods for the determination of toxic organic. The canister is prepared for sampling by evacuating the contents to a vacuum of approximately 29. Unfortunately, careful study of the most widely used solid.
Using a 916 wrench, remove the brass cap from the valve on the top of the summa canister. A summa canister is a stainless steel container that has had the internal surfaces specially. This procedure outlines the steps required to complete automated sampling of summa canisters for the analysis of the specific volatile organic compounds voc for the wbea network. The canister will be provided by the laboratory, along with a. For summa canister samples, trip blanks will be included for each day sampling is performed. The method is based on samples collected as whole air samples in summa passivated stainless steel canisters. Canisterbased method for monitoring toxic vocs in ambient air.
Pitfalls and pratfalls of sampling via summa canister. Summa canisters have a much longer holding time and are more rugged, but are more expensive and cannot be used for more reactive compounds such as those containing sulfur and nitrogen unless they have been modified with an inert lining. Btex mix in nitrogen 10 ppm each component in nitrogen, cylinder of 48 l. To14 summa canister sampling epa to methods sigmaaldrich. This is a 24hour method of sampling and follows epa toxic organics method to 15.
To support the clients air sampling project, eurofins mgt provides the media necessary for sample collection. The size of can ister used usually depends on the concentration of the analytes in the sample, the sampling time, the flow rate, and the sample volume required for the sampling period table ii, page 3. Teflon tubing supplied by laboratory summa canister fittings and ferules supplied by laboratory. A vacuumpressure gauge 030 in hg and 030 psig can be attached to canister as an option. Details of this sampling effort are presented in the technical memorandum dated 14 may 2002, which is provided in the back of this appendix. Stop sample collection after the scheduled duration of sample collected, but when the canister still has a minimum amount of vacuum remaining. Thus, surface inertness for silcocan canisters exceeds that for summa and tocan. To15 summa canister sampling solutions for sites requiring conventional to15 summa canister samples for soil gas collection, eurofins can provide additional sampling equipment to assist with purging lines prior to collection, conducting leak checks on the train, monitoring vacuum at the extraction probe and performing an equipment train blank. Vocs by epa method to15a collection by summa canister analysis by cryofocusing gcms sample is cooled to. Sampling is achieved by soil gas equilibration with the evacuated summa canister. Excellent analyte recovery even aft er 14 days of storage. In contrast, the solid sorbent approach to sampling vocs places the sorbent as the first element in the sampling train.
Other field air monitoring devices, such as the combustible gas indicator msa cgi02 meter, model 260 and the organic vapor analyzer foxboro ova, model 128, can also be used. Mike day everything about concrete recommended for you. In canister sampling, two sampling techniques are commonly used. Ensure valve is closed, remove brass cap, and continue with canister sampling instructions for a grab sample or time integrated sample. Epa method to15 cites a sample hold time of up to 30. For grab sampling, the canister valve is simply opened. Finally, tedlar bag sampling requires a pump, while summa canister sampling does not. Collection of whole air sampling can be either active requires a pump or passive no pump required.
Submission of summa canister passive sampler order form will be deemed as acceptance of the general media agreement. Cox, cpg evacuated stainlesssteel canisters canisters sampled via method to15 are widely considered to be the gold standard for air sampling. An air sampling canister is a container for collecting a whole air. Pitfalls and pratfalls of sampling via summa canister by. Results of the lowflow voc air samples indicated concentrations below the method detection limits. For cleaning and certification of summa canisters, follow the requirements specified in sections 7. When sampling using a canister, there are two sampling approaches. Using summa canister sampling and gas chromatography gc analysis.
Flow controller is connected to the valve of the summa canister to regulate air flow over a specific time period e. Canister flow controller flow controller is connected to the valve of the summa canister to regulate air flow over a specific time period e. For grab sampling, the canister valve is simply opened and the. Jul 24, 20 how to form, pour, and stamp a concrete patio slab duration. The vessel, also known as a summa canister, was cleaned and evacuated in the laboratory. Evacuated stainlesssteel canisters canisters sampled via method to15 are widely considered to be the gold standard for air sampling. Two leak tests one for the sampling train and one for the sample probe should be conducted for every subslab vapor sample in order to establish air tightness. Standard operating procedure for the collection of. Within a few years, to14 began to replace to1to2 as the method of choice.
Summa canisters variety of sizes, depending on the application 6 liter. Final report section ozone, passive sampling with summa. In 1982, the epa compendium of methods for the determination of vocs in ambient air first appeared which specified the use of summa passivated. Pitfalls and pratfalls of sampling via summa canister cox. Summa or silco canister cleaned and certified by als, and leak checked prior to shipment. Canisterbased method for monitoring toxic vocs in ambient. Initiate the sampling event by turning valve on canister counter clockwise until valve does not turn anymore. Canisterbased sampling of toxic volatile organic compounds vocs is being used for many ambient air voc monitoring programs in the united states. Portable instruments users manual for monitoring voc sources, epa340188015, u. How to form, pour, and stamp a concrete patio slab duration. Soil vapour sampling using summa canisters presented by maxxam analytics.
The summa canister is a commercially available sampling system. A summa canister is a stainless steel electropolished or summa polished passivated vessel used to collect a whole air sample. Canisters are stored in an evacuated state of less than 0. A summa canister is a stainless steel container that has had the. Each canister should be observed for an attached sample identification number. In passive sampling, an air sample is pulled through a flow controller into an evacuated canister over a chosen period of time, ranging from 5 minutes to. Volatile organic compounds vocs in ambient air using summa. Summa canister sampling procedure critical orifice flow controller complete setup procedure. Testing for volatile organic compounds in source air by gc. Canisters are evacuated to kpa 2 psi, then filled with clean, humidified nitrogen to 172 kpa 25 psi, while heated to 80c. Vapor sampling devices summa canisters passive samplers. A canister may be spherical or cylindrical and is constructed of specially treated stainless steel.
The main difference to the sampling method employed with to1to2 was that a stainless steel vessel that resembles a basketball with a metal frame and valve was used to collect the sample. Detection limits are dependent on the instruments not the size of the canister. Sampling into stainless steel canisters was first conducted to measure freons in the atmosphere to help scientists determine which compounds were responsible for the depletion of the ozone layer. Air sampling method fact sheet hill air force base. Each has advantages and disadvantages, and at many sites more than one of these devices are used. Subslab soil vapor sampling equipment individually cleaned and certified summa canisters with individual 200 mlmin flow controllers and individual pressure gauges supplied by laboratory. Uses vacuum of canister to pull sample however, flow controller maintains constant flow to a point. The vessel, also known as a summa canister was cleaned and evacuated in the laboratory. Equipment needed and practical techniques for collecting air samples. Please do not move or adjust the valve thereafter until the sampling is. The results of the summa canister sampling indicated no contaminants above the osha. These devices are designed to collect a sample over a period of 14 to 26 days. Detection limits are dependent on the instruments not the size of the.
Much of the guidance recommends or requires the use of canisters for vapor intrusion vi sampling, but. The suitability of adsorbent cartridges for passive sampling of oil and natural gas voc was evaluated using several approaches, discussed in the following. Summary of method this canister sampling sop describes procedures for sampling with canisters at final. Slide the nut on to the tubing, followed by the ferrule, as shown below. It can take grab samples intermittently, or over a period of time. To collect a sample, the summa canister valve is opened and the canister is left in a designated area for a period of time to allow the surrounding air to fill the canister and achieve a representative sample. The summa canisters are described in epa method to15, and are commonly used for the collection of volatile organic compounds vocs in ambient and indoor air. Volatile organic compounds vocs in ambient air using. Other things being equal, this ordering would be a reason to favor the use of solid sorbents. The samples are collected as whole air samples in passivated summa or silco lined. Each canister is recorded in the dedicated laboratory logbook by its summa canister number. Epa method to15 cites a sample hold time of up to 30 days for most.
Collaborate with the assigned dnr project manager prior to using leak testing methods not outlined below. Therefore, to have a valid sample the canister should not be allowed to come to ambient pressure 0 psig. Change to air sampling method improves sample accuracy september 2019 passive diffusion samplers, shown here, replaced summa canisters. Vapor sampling devices today there are a number of types of equipment that can be used to measure vapor concentrations in air and soil gas. Position the canister in the predetermined secure location.
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